Anisotropy of the spectroscopic, optical and thermo-mechanical properties of Li6Eu1-xGdx(BO3)3 crystals optimized for heat-scintillation cryogenic bolometers

Rekia Belhoucif (1, 2, 3) , Matias Velázquez (1) , Yannick Petit (1) , Olivier Plantevin (4) , Marcos A. Couto dos Santos (5) , Frédéric Adamietz (6) , Vincent Rodriguez (6) , Michel Couzi (6) , Olivier Pérez (7) , Oudomsack Viraphong (1) , Philippe Veber (1) , Dominique Denux (1) , Djamel Ouadjaout (8) , Rodolphe Decourt (1)

1 ICMCB - Institut de Chimie de la Matière Condensée de Bordeaux
2 USTHB - Université des Sciences et de la Technologie Houari Boumediene = University of Sciences and Technology Houari Boumediene [Alger]
3 UMBB - Université M'Hamed Bougara Boumerdes
4 CSNSM - Centre de Sciences Nucléaires et de Sciences de la Matière
5 UFS - Federal University of Sergipe = Université fédérale de Sergipe
6 ISM - Institut des Sciences Moléculaires
7 CRISMAT - Laboratoire de cristallographie et sciences des matériaux
8 Centre de Recherche en Technologie des Semiconducteurs pour l’Energétique (CRTSE)

Optical, spectroscopic and thermo-mechanical properties of monoclinic Li6Eu1-xGdx(BO3)3 (x = 0,0.25,0.35) bulk single crystals, grown to be used in the design of heat-scintillation cryogenic bolometers (HSCBs), were investigated. The linear thermal expansion was determined along the a, b, c and c* directions over the temperature range 303–873 K, and its tensor principal coefficients were calculated for both x = 0.25 and x = 0. In addition, the anisotropic thermal conductivity was measured over the temperature range 20-400 K in Li6Eu0.75Gd0.25(BO3)3 (LGEB7, x = 0.25), and the principal components of its tensor at 300 K were established. Spectroscopic properties such as polarized absorption, polarized emission, Raman spectroscopy and optical refractive indices are also reported for the first time. Based on the polarized emission spectra, the line and oscillator strengths, the radiative lifetimes and fluorescent branching ratios were obtained. The intensity parameters Ωλ (λ = 2,4) were obtained and then predicted via the Judd–Ofelt theory. The crystal field parameters and the 7F1 level splitting were discussed using the simple overlap model (SOM) and the method of equivalent nearest neighbours (MENN). The 613 nm emission originates from the 5D0→7F2 transition and the associated stimulated emission peak cross section reaches its maximum value in π-polarization, ≈1.07 × 10−20 cm2 in LGEB7. The thermo-mechanical characterizations and spectroscopic analysis in LGEB7 suggest that this crystal has better optical properties than the Eu3+-doped Li6Y(BO3)3 crystals. However, its potential for solid-state laser applications is still quite speculative, unless a clever thermo-mechanical management of the crystal under laser operation is designed.

Mots clés: Thermal-properties; Field parameters; Energy-transfer; Single-crystas; Simple overlap model; Expansion; Absorption; Fluorescence; Luminescence; Growth; OCIS codes: (0406070) Solid state detectors; (1204530) Optical constants; (1403380) Laser materials; (1405680) Rare earth and transition metal solid-state lasers

Domaines: Matériaux

Rekia Belhoucif, Matias Velázquez, Yannick Petit, Olivier Plantevin, Marcos A. Couto dos Santos, et al.. Anisotropy of the spectroscopic, optical and thermo-mechanical properties of Li6Eu1-xGdx(BO3)3 crystals optimized for heat-scintillation cryogenic bolometers. Optical Materials Express, 2014, 4 (10), pp.2042-2065. ⟨10.1364/OME.4.002042⟩. ⟨hal-01108446⟩