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Regioselective C–H amination of free base porphyrins via electrogenerated pyridinium-porphyrins and stabilization of easily oxidized amino-porphyrins by protonation

Abstract : Four free base aminoporphyrins were synthesized in two steps via regioselective anodic nucleophilic substitution with pyridine followed by ring opening of the electrogenerated pyridinium with piperidine.
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https://hal.archives-ouvertes.fr/hal-03419593
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Submitted on : Monday, November 8, 2021 - 3:42:15 PM
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Asmae Bousfiha, Abdou Dimé, Amelle Mankou-Makaya, Julie Echaubard, Mathieu Berthelot, et al.. Regioselective C–H amination of free base porphyrins via electrogenerated pyridinium-porphyrins and stabilization of easily oxidized amino-porphyrins by protonation. Chemical Communications, Royal Society of Chemistry, 2020, 56 (6), pp.884-887. ⟨10.1039/c9cc07351e⟩. ⟨hal-03419593⟩

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