Preparation of well-defined 2D-lenticular aggregates by self-assembly of PNIPAM- b -PVDF amphiphilic diblock copolymers in solution

Enrique Folgado (1, 2) , Matthias Mayor (1) , Didier Cot (1) , Michel Ramonda (3) , Franck Godiard (4) , Vincent Ladmiral (1) , M. Semsarilar (2)

1 IEM - Institut Européen des membranes
2 ICGM - Institut Charles Gerhardt Montpellier - Institut de Chimie Moléculaire et des Matériaux de Montpellier
3 Centrale de Technologie en Micro et Nanoélectronique CTM-­LMCP
4 UM - Université de Montpellier

PNIPAM- b -PVDF amphiphilic block copolymers were synthesized via RAFT polymerization in dimethyl carbonate. These block copolymers were able to self-assemble into various morphologies such as spherical, crumpled, lamellar and lenticular 2D aggregates.

Domaines: Chimie

Enrique Folgado, Matthias Mayor, Didier Cot, Michel Ramonda, Franck Godiard, et al.. Preparation of well-defined 2D-lenticular aggregates by self-assembly of PNIPAM- b -PVDF amphiphilic diblock copolymers in solution. Polymer Chemistry, 2021, 12 (10), pp.1465-1475. ⟨10.1039/D0PY01193B⟩. ⟨hal-03377912⟩